Semiconductor Greases and Oils

Advantages of Semiconductor Greases and Oils

NyeTorr®, NyeClean® and NyeVac® are specialty lubricants formulated specifically for Semiconductor fabrication and processing equipment. These low outgassing semiconductor lubricants are chemically stable even when exposed to process gasses, making them the first choice of leading Semicon equipment OEMs and fabricators.

Features & Benefits:

Reduce friction & wear
Extend component life
Prevent contamination
Withstand vacuum conditions

Improve functionality & reliability
Improve line yields
Avoid latent defects
Increase uptime

What Characteristics Should Be Considered When Selecting a Semicon Lubricant?

LOW OUTGASSING

When a lubricant outgasses it releases condensable material that can contaminate wafers, processing equipment, and other sensitive components. Lubricant outgassing is measured in total mass loss (TML) and collected volatile condensable materials (CVCM) per ASTM E595. Nye’s lubricants fall well below the acceptable outgassing limits determined by the semiconductor industry, 1% or less for TML and 0.10% or less for CVCM. Nye can collect these condensable materials and conduct Residual Gas Analysis (RGA) to identify the materials shed from the lubricant into a system.

LOW PARTICLE GENERATION

The term dynamic particle generation describes what happens when contaminants are created by being forced or expelled from a lubricated ball-screw, bearing, or gear system into the operating environment. These contaminants could include base oil constituents, thickener particles, additives, etc. and are freed from the grease through dynamic mechanical action whether it be rolling, sliding, or a combination of both. Engineers in Nye’s Application Development and Validation Test Lab developed a proprietary test method and apparatus that measures and quantifies particle generation under these dynamic conditions. Results from this test provide valuable data that can be used to inform the development of specialty lubricants with low particle generation.

HIGH TEMPERATURE CAPABILITY

A lubricant must be able to protect the mechanical components of fab equipment at high temperatures without evaporating. Outgassing is more likely to happen at high temperatures as vapor pressure increases. Many of Nye’s in-vacuum and cleanroom lubricants are formulated to perform at temperatures up to 250 °C.

LUBRICANT CLEANLINESS LEVELS

Manufacturing equipment in vacuum and cleanroom environments are highly sensitive, where even microscopic particulates can cause product failure. The best way to ensure lubricant cleanliness is through ultrafiltration to eliminate microscopic particulates in a lubricant. Nye can ultrafilter grease and oil to eliminate possible contaminants for semiconductor applications.

PFOA-COMPLIANCE

All Nye products for the Semiconductor Industry use PTFE with levels of PFOA less than 0.1% by weight, in compliance with REACH guidelines and other international regulations. Although this work is not a measurement of each product's complete formulation, analysis indicates PTFE would be the most significant contributor to PFOA levels.

PFPE vs MAC lubricants

Both PFPE and MAC lubricants are recommended for vacuum environments because of their low vapor pressure, and low outgassing. PFPE lubricants offer better high temperature performance (up to 250° C) when compared to MAC lubricants (up to 150° C). Because of their unique additive packages, MAC lubricants provide better protection against wear when compared to PFPE lubricants. Both chemistries can be ultrafiltered, are compatible with plastics and elastomers, and comply with PFOA regulations.

NyeTorr vs NyeClean

NyeTorr® and NyeClean® products are chemically stable, non-toxic, low-vapor-pressure, synthetic lubricants for semiconductor components like bearings, linear guides, ball screws, and other sensitive mechanisms. NyeTorr® products are recommended for use in ultra-high vacuum applications exposed to high temperatures. NyeClean® products have good low particle generating properties and are recommended for cleanroom applications like back-end packaging where little or no vacuum is present.

PFPE GREASES

Product	Kinematic Viscosity @ 40°C	Vacuum Stability (ASTM E595)	Features
NYECLEAN 5057	192 cSt	TML= 0.225 wt% CVCM= 0.054 wt%	Suggested alternative for discontinued legacy PFPE semiconductor greases.
NYECLEAN 5097R	140 cSt	TML= 0.441 wt% CVCM= 0.044	Provides superior corrosion resistance and wear performance up to 180° C in environments where outgassing is not a concern.
NYETORR 5300	140 cSt	TML= 0.320 wt% CVCM= 0.045 wt%	Industry standard PFPE vacuum grease.
NYETORR 5300XP	140 cSt	TML= 0.075 wt% CVCM= 0.018 wt%	Offers improved wear performance in high load applications.
NYETORR 5350	152 cSt	TML=0.757 wt% CVCM=0.451 wt%	Suitable for low to moderate vacuum conditions with improved load and wear performance.
NYETORR 6300	188 cSt	TML= 0.036 wt% CVCM= 0.006 wt%	Significantly lower outgassing rates.
NYETORR 6300S	188 cSt	TML= 0.012 wt% CVCM= 0.000 wt%	A soft grease used in applications that require lower viscous drag and torque resistance.
NYETORR 6350EL	200 cSt	TML = 0.060 wt% CVCM = 0.008 wt%	Offers Lube-For-Life performance in applications that require low outgassing and low torque.
NYETORR 6370EL	362 cSt	TML= 0.063 wt% CVCM= 0.001 wt%	Offers the longest life of any PFPE lubricant while providing superior corrosion and wear resistance.

MAC GREASES

Product	Kinematic Viscosity @ 40°C	Vacuum Stability (ASTM E595)	Features
NYETORR 5200	108 cSt	TML= 0.068 wt% CVCM= 0.007 wt%	Superior torque and anti-wear performance to extend component life.
NYETORR 6200	108 cSt	TML= 0.058 wt% CVCM= 0.025 wt%	Superior outgassing and anti-wear performance.
NYETORR 6200-FL	108 cSt	TML=0.03 wt% CVCM=0.007 wt%	Excellent torque performance in low-speed dithering operations.

PFPE OILS

Product	Kinematic Viscosity @ 40°C	Vacuum Stability (ASTM E595)	Features
NYETORR 5301	140 cSt	TML= 0.230 wt% CVCM= 0.033 wt%	Base oil used in NyeTorr® 5300.
NYETORR 6301	187 cSt	TML= 0.00 wt% CVCM= 0.000 wt%	Base oil used in NyeTorr® 6300.
NYETORR 5361	192 cSt	TML= 0.03 wt% CVCM= 0.010	Base oil used in NyeClean® 5057.
NYETORR 6371	446 cSt	TML= 0.020 wt% CVCM= 0.002 wt%	Base oil used in NyeTorr® 6370EL.
NYETORR 5381	809 cSt	TML= 0.070 wt% CVCM= 0.004 wt%	Used as a grease replacement for static seals where a degree of damping is needed.

MAC OILS

Product	Kinematic Viscosity @ 40°C	Vacuum Stability (ASTM E595)	Features
NYETORR 5201	108 cSt	TML= 0.120 wt% CVCM= 0.013 wt%	Base oil used in NyeTorr® 5200.
NYETORR 6201	108 cSt	TML= 0.110 wt% CVCM= 0.010 wt%	Base oil used in NyeTorr® 6200.
SYNTHETIC OIL 3001A	2082 cSt	TTML=0.100 wt% CVCM= 0.050wt%	An ultra-filtered oil for loaded applications requiring excellent film strength.

Testing & Manufacturing

The materials and manufacturing methods used to prepare a lubricant can impact lubricant cleanliness. At Nye, the raw materials are required to meet stringent quality standards. The in-vacuum lubricants are manufactured and packaged in ISO Class 8 and Class 7 certified clean rooms to ensure the products are suitable for your manufacturing environment.

All of Nye’s products can also be tested under vacuum and high temperatures in our Vacuum Aerospace Semiconductor Test (VAST) Laboratory. Tests performed under these simulated operating conditions provide the customers with accurate outgassing, particle generation, and other important performance data that help them select the right lubricant for their precision fab equipment and high-end manufacturing processes. Nye’s unique materials, such as Pennzane, and manufacturing methods, such as Ultrafiltration, have been proven to withstand the harshest conditions, on earth and in space, for nearly 50 years.